Product ID:CINEREX CP FIXER WORKING STRENGTH
MSDS Date:03/17/1998
FSC:NIIN:Submitter:F BT
Status Code:A
MSDS Number: CLMDB

Emergency Phone: 303-623-5716

Info Phone: 201-440-2500

Preparer: R. RUPPEL-KERR

Cage: 1MVW0

Telephone: 201-440-2500

Cage: 1MVW0

WATER

CAS: 7732-18-5

RTECS: ZC0110000

AMMONIUM THIOSULFATE

CAS: 7783-18-8

RTECS: XN6465000

SODIUM SULFITE

CAS: 7757-83-7

RTECS: WE2150000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE EYE, SKIN, AND RESPIRATORY
TRACT IRRITATION; MAY CAUSE ALLERGIC RESPIRATORY REACTION; MAY
CAUSE ALLERGIC SKIN REACTION; IRRITATING GASES/FUMES MAY BE GIVEN
OFF DURING BURNING OR THERMAL DECO MPOSITION.
Effects of Overexposure:INHALATION:INHALATION OF AMMONIUM THIOSULFATE
AND SODIUM SULFITE VAPORS MAY BE IRRITATING TO THE RESPIRATORY
TRACT AND CAN CAUSE A SORE THROAT, COUGHING, AND RUNNY NOSE.
BRONCHOCONSTRICTION, SWEATING, FLUSHING, HIVES, RAPID HEART RATE,
DECREASED BLOOD PRESSURE, AND ANAPHYLAXIS. SKIN:REDDENING AND
ITCHING. EYE:MAY BE IRRITATING TO THE EYES AND CAN CAUSE REDDENING,
TEARING, AND STINGING. INGESTION: MAY CAUSE GASTROINTESTINAL
IRRITATION.
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING EYE, SKIN
OR RESPIRATORY TRACT DISORDERS MAY BE MORE SUSCEPTIBLE TO THE
EFFECTS OF THIS PRODUCT.

First Aid:EYES: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES. SKIN: REMOVE CONTAMINATED CLOTHING, IMMEDIATELY
WASH SKIN WITH PLENTY OF WATER. WASH CLOTHING BEFORE REUSE.
INHALATION: RE MOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IN ALL CASES, SEEK IMMEDIATE MEDICAL ATTENTION!

Flash Point:NONCOMBUSTIBLE
Extinguishing Media:MATERIAL IS NOT COMBUSTIBLE. USE EXTINGUISHING
MEDIA SUITABLE FOR OTHER COMBUSTIBLE MATERIALS IN THE AREA.
Fire Fighting Procedures:EVACUATE PERSONNEL TO A SAFE AREA. KEEP
PERSONNEL REMOVED AND UPWIND OF FIRE. WEAR SELF-CONTAINED
BREATHING APPARATUS. COOL CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION EMISSION OF
TOXIC FUMES OF SO2 IS POSSIBLE.

Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT
DURING CLEAN UP. DIKE SPILL. PREVENT LIQUID FROM ENTERING SEWERS,
WATERWAYS OR LOW AREAS. SOAK UP WITH SAWDUST, SAND, OIL DRY OR
OTHER ABSORBENT MATERI AL.

Handling and Storage Precautions:STORE BETWEEN 40 F AND 80 F. PREFERRED
STORAGE IS AT 68 F. KEEP FROM FREEZING. AVOID EYE & SKIN
CONTACT,AND STORE IN WELL VENTILATED AREA. KEEP CONTAINER TIGHTLY
CLOSED. DO NOT STORE WITH INCOMPATIBLE MATERIALS. DO NOT STORE OR
CONSUME FOOD,DRINK OR TOBACCO IN AREA WHERE THEY MAY BECOME
CONTAMINATED
Other Precautions:KEEP OUT OF THE REACH OF CHILDREN.

Respiratory Protection:UNDER NORMAL CONDITIONS OF USE, RESPIRATOR
PROTECTION IS NOT REQUIRED. IF RESPIRATORS ARE USED, INSTITUTE A
PROGRAM IN ACCORDANCE WITH OSHA STANDARD 29CFR10.10.134.
Ventilation:USE SUFFICIENT GENERAL ROOM VENTILATION AND/OR LOCAL
EXHAUST TO MAINTAIN AIRBORNE LEVELS OF VAPORS BELOW APPLICABLE
EXPOSURE LIMITS.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:SAFETY GLASSES OR GOGGLES
Other Protective Equipment:APRONS. EMERGENCY SHOWERS AND EYE WASH
STATIONS SHOULD BE MADE AVAILABLE. EDUCATE AND TRAIN EMPLOYEES IN
THE SAFE USE AND HANDLING OF THIS PRODUCT.
Supplemental Safety and Health
HMIS RATINGS: HEALTH=2, FLAMMABILITY=0, REACTIVITY=0

Boiling Pt:=100.C, 212.F
Spec Gravity:1.10
pH:4.4
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR LIQUID WITH A SLIGHT SULFUR DIOXIDE ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG ALKALI, STRONG ACIDS, OXIDIZERS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:OXIDES OF SULFUR, CO2, CARBON
MONOXIDE, AMMONIA.

Waste Disposal Methods:RECOVER NONUSABLE FREE LIQUID AND/OR
CONTAMINATED WATER, AND DISPOSE OF IN AN APPROVED AND PERMITTED
TREATMENT SYSTEM. REMOVE NONUSABLE SOLID MATERIAL AND/OR
CONTAMINATED SOIL, FOR DISPOSAL IN AN APP ROVED AND PERMITTED
LANDFILL. DISCHARGE TO SEWER MAY REQUIRE APPROVAL OF PERMITTING
AUTHORITY & MAY REQUIRE PRETREATMENT.

Toxicological Information:NO ANIMAL TOXICITY INFORMATION AVAILABLE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO ECOLOGICAL INFORMATION AVAILABLE.

Transport Information:TECHNICAL SHIPPING NAME: AQUEOUS PHOTOCHEMICAL
SOLUTION ; PRODUCT LABEL: CINEREX CD FIXER WORKING STRENGTH.

SARA Title III Information:SECTION 311/312 HAZARD CATEGORIES: IMMEDIATE
HEALTH HAZARD
Federal Regulatory Information:OSHA STATUS: THIS PRODUCT IS HAZARDOUS
UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD COMMUNICATION
STANDARD 29 CFR 1910.1200.; TSCA STATUS: ON TSCA INVENTORY; RCRA
STATUS: IF DISCARDED IN ITS PURCHASE D FORM, THIS PRODUCT WOULD NOT
BE A HAZARDOUS WASTE EITHER BY LISTING OR BY CHARACTERISTIC.
HOWEVER, UNDER RCRA, IT IS THE RESPONSIBILITY OF THE PRODUCT USER
TO DETERMINE AT THE TIME OF DISPOSAL, WHE THER A MATERIAL
CONTAINING THE PRODUCT OR DERIVED FROM THE PRODUCT SHOULD BE
CLASSIFIED AS A HAZARDO US WASTE.
State Regulatory Information:AMMONIUM THIOSULFATE-STATE CODE: NEW
JERSEY, PENNSYLVANIA, MASSACHUSETTS; SODIUM SULFITE-STATE
:PENNSYLVANIA, NEW JERSEY; WATER-STATE CODE:PENNSYLVANIA, NEW
JERSEY.